North Dakota State University
NDSU Extension Service
E-1143, January 2005
For use in 2005 only

2005 Field Crop Insect Management Recommendations
compiled by Phillip Glogoza, Extension Entomologist,
in cooperation Janet Knodel, Mark Boetel, Denise Olson, and Gary Brewer
Department of Entomology
North Dakota State University


North Dakota
Pesticide Poison Information
Toll - Free Number
(800) 222 - 1222

The Effect of Water pH on Insecticides

In recent years, another consideration in the application of insecticides is the pH of the water to be used for spraying. This is particularly important when organophosphate and carbamate insecticides such as Guthion, parathion, malathion, carbaryl and others are to be used. Experience in the Red River Valley area of North Dakota indicates that water with a pH of 8.0 _ 8.2 or higher will cause rather rapid degradation of these insecticides while in solution. Buffering effects occur while the insecticide is in the spray solution, from mixing, through storage in the tank and continues until the water has evaporated from the spray droplet lying on the leaf.

Half-Life* of Some Insecticides At Different Water pH  

Insecticide
Product
Buffering Advised Optimum pH Half-Life for given pH
9.0 8.0 7.0 6.0 5.0 4.0
Actara   7.0 Susceptible to alkaline hydrolysis in pH<9.0
Actellic   7.0   12 days 35 days   7 days  
Admire   6.0 355 days   Fully stable at a pH of 5 and 7  
Ambush
(permethrin)
  7.0   Stable at pH 6.0 - 8.0    
Asana XL   7.0 Stable over a pH 5.0 - 9.0 range  
Di-Syston X 5.0 7.2 hours     32 hours 60 hours  
Diazinon   7.0 29 days   70 days   14 days  
Dibrom X 5.0 Hydrolized in 48 hours In pH > 7      
Dimethoate / Digon X 5.0 48 min.     12 hours   20 hours
Dipel (Bac.)   6.0 Unstable in pH>8.0        
Furadan X 5.0 78 hours     8 days    
Guthion X 5.5 12 hours   10 days   17 days  
Imidan X 5.0   4 hours 12 hours     13 days
Lannate   6.5       stable in slightly acidic water
Lindane     11 days   27 weeks      
Lorsban   7.0   1.5 days 35 days   63 days  
Malathion X 5.0 5 hours 19 hours 3 days 8 days    
Monitor X 5.5 Decomposes rapidly at pH > 7      
Orthene (acephate)   7.0 16 days   46 days   40 days  
Pounce (permethrin)   7.0     Stable at pH 6.0 - 8.0  
Provado   7.0 Stable over wide range of pH
Reldan   7.0   3 days   38 days   10 days
Sevin (carbaryl) X 7.0 24 hours 2.5 days 12 days      
Spintor   7.0 Stable in pH from 6.0 to 11.0 12 hours  
Thiodan   6.5 some alkaline hydrolosis      
Vydate X 5.0 3 hours   8 days   stable at 4.7 pH
Warrior   6.0     stable in pH 4.5 - 7.5

* Half-life is the time it takes for 50% of the chemical to decompose


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